Product ID:FREON TF 60#
MSDS Date:12/22/1988
FSC:6850
NIIN:00-033-8851
MSDS Number: BSRWF

Emergency Phone: 606-324-1133

Info Phone: 614-889-3333

Cage: 5A188

Telephone: 614-889-4505

Cage: 5A188

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYE:MAY CAUSE DISCOMFORT,USUALLY
NO EXTENDED EFFECT.SKIN:PROLONGED/REPEATED CONTACT CAN CAUSE
MODERATE IRRITATION,DEFATTING,DERMATITIS.INHALATION:HIGH
CONCENTRATIONS OF VAPOR CAN CAUSE NARCOSIS, CARDIAC
IRREGULARITIES,UNCONSCIOUSNESS/DEATH.INGESTION:MAY CAUSE
IRRITATION.LOW TOXICITY.CHRONIC-NOT GIVEN.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, SKIN
IRRITATION/DEFATTING/DERMATITIS, NARCOSIS, CARDIAC IRREGULARITIES,
UNCONSCIOUSNESS, DEATH, GASTROINTESTINAL IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:GET MEDICAL ATTENTION-EYE:FLUSH W/WATER 15 MIN,HOLD LIDS
OPEN.SKIN:WASH WITH SOAP & WATER.INHALED:REMOVE TO FRESH AIR. GIVE
CPR/OXYGEN IF NECESSARY.KEEP VICTIM WARM & QUIET.DON'T GIVE
STIMULANTS.EPINE PHRINE MAY ADVERSELY AFFECT THE HEART WITH FATAL
RESULTS.IF SWALLOWED:DON'T INDUCE VOMITING.KEEP PERSON WARM &
QUIET.ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN
CAUSE CHEMICAL PNEUMONITI

Flash Point:NOT RELEVANT
Extinguishing Media:NON FLAMMABLE.USE WATER FOG,CARBON DIOXIDE/DRY
CHEMICAL FOR SURROUNDING FIRE.USE WATER TO COOL FIRE-EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN
FIGHTING FIRES.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:REMOVE FLAMES,HEATING ELEMENTS, GAS ENGINE,
ETC..WEAR PROTECTIVE EQUIPMENTS.ABSORB SMALL SPILLS ON
PAPER,VERMICULITE,.. STOP LEAK FOR LARGE SPILLS.DIKE AREA.PUMP
LIQUID TO SALVAGE TANK.TAKE UP THE RES T BY SAND/CLAY AND SHOVEL TO
A CONTAINER.
Neutralizing Agent:NONE GIVEN

Handling and Storage Precautions:STORE CONTAINERS TIGHTLY CLOSED IN A
COOL, WELL VENTILATED PLACE,AWAY FROM HEAT,SPARKS & FLAMES.EMPTY
CONTAINER MAY CONTAIN HAZARDOUS RESIDUES.
Other Precautions:OBSERVE ALL PRECAUTIONS GIVEN IN THE DATA SHEET.

Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT OF PRODUCT EXCEEDS
THE TLV, A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION.
Protective Gloves:BUTYL RUBBER
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:DO NOT INHALE VAPORS. WASH HANDS BEFORE EATING
AND DRINKING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:N1
Boiling Pt:B.P. Text:118F,48C
Vapor Pres:334
Vapor Density:6.5
Spec Gravity:1.565
Evaporation Rate & Reference:0.1 (CARBON-TETRA-CL = 1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI METALS,ALKALINE EARTH METALS,POWDERED ALUMINUM, ZINC, BERYLLIUM
ETC..
Stability Condition to Avoid:HIGH TEMPERATURES AND FLAMES
Hazardous Decomposition Products:HYDROGEN FLUORIDE AND CHLORIDE,
CARBONYL HALIDES, ETC..

Waste Disposal Methods:CONSULT FEDERAL, STATE AND LOCAL AUTHORITIES FOR
PROPER DISPOSAL PROCEDURES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.